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Sensors

Zenan Bao further develops stretchable, potentially reshapeable, skin inspired electronics

Stanford’s Zhenan Bao and team have developed a stretchable, potentially reshapeable, wearable display that can allow a new way of interactive human-machine interface. “We can see the image and interact with it, and then the display can change according to our response” said Bao in a Stanford interview.

The display is made entirely of stretchy polymers, with a maximum brightness of twice that of a cellphone. It can be stretched to twice its original length without tearing.

Most light-emitting polymers are crack when stretched. Flexibility can be increased with elastic insulating materials, which decrease electrical conductivity, and require a dangerously high voltage.

Postdoc Zhitao Zhang discovered that a yellow-colored light-emitting polymer called SuperYellow became soft and pliable, and emitted brighter light when mixed with a type of polyurethane. The interconnected net of nanoscale fibers that make the SuperYellow stretchy don’t inhibit electricity flow. The group also created elastic red, green and blue light-emitting polymers.

The final display contains seven layers. Two outer layers are two substrates that encapsulate the device. Two inner electrode layers follow, each followed by charge transporting layers. The light-emitting layer is sandwiched in the center.

When electricity runs through the display, one electrode injects positive charges, called holes, into the light-emitting layer, while the other injects negatively charged electrons into it. When the two types of charges meet, they bond and go into an energetically excited state. Almost immediately, the state returns to normal by producing a photon.

The resulting all-polymer film can adhere to an arm or finger and doesn’t rip during bending or flexing. This allows wearable tracker displays to directly attach to skin.

Bao imagines “a display where you can both see and feel the three-dimensional object on the screen. This will be a completely new way to interact with each other remotely.”


Join ApplySci at MIT on September 30, 2022 for the 14th Deeptech Health + Neurotech Conference

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Featured Sensors

Stretchable, degradable semiconductors for health monitoring

Zhenan Bao has developed stretchable, degradable semiconductors, with the ability to conform to internal organ surfaces, and dissolve and disappear when no longer needed.

This is the first example of a material that simultaneously possesses the three qualities of semiconductivity, intrinsic stretchability and full degradability. Other attempts resulted in semiconductors that either did not break down completely, or had reduced electrical performance when stretched.

Zhenan Bao has solved this problem – by combining a rubbery organic polymer with a semiconducting one.

Her team synthesized and mixed the two degradable polymers, which self-assembled into semiconducting nanofibers embedded in an elastic matrix. Thin films made of these fibers could be stretched to twice their normal length without cracking or compromising electrical performance. When placed in a weak acid, the new material degraded completely within 10 days.   (Bao said that it would take much longer in the human body.) The semiconductor was  non-toxic to human cells growing on the material in a petri dish.


Zhenan Bao will discuss this technology, and more of her latest work, at Wearable Tech + Digital Health + Neurotech Silicon Valley on Feb 11-12